6325-63-9

Basic information

• Product Name: Benzene,1,1'-(1,2-ethenediyl)bis[3-methoxy-
• Synonyms: Stilbene,3,3'-dimethoxy- (7CI,8CI); NSC 30994
• CAS NO: 6325-63-9
• Molecular Formula: C16H16 O2
• Molecular Weight: 240.302
• Mol File: 6325-63-9.mol
• Article Data: 36

Chemical Properties

• Boiling Point: 372.7°Cat760mmHg
• Flash Point: 148.4°C
• Density: 1.089g/cm³
• CAS DataBase Reference: Benzene,1,1'-(1,2-ethenediyl)bis[3-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1,1'-(1,2-ethenediyl)bis[3-methoxy-(6325-63-9)
• EPA Substance Registry System: Benzene,1,1'-(1,2-ethenediyl)bis[3-methoxy-(6325-63-9)

Safety Data

• Hazardous Substances Data: 6325-63-9(Hazardous Substances Data)

Upstream product

• 691-38-3 (Z)-4-methyl-2-pentene 
• 110-82-7 cyclohexane 
• 65864-99-5 1-(diazomethyl)-3-methoxybenzene 
• 19350-71-1 N'-(3-methoxybenzylidene)-4-methylbenzenesulfonohydrazide 
• 1711-05-3 m-anisoyl chloride 
• 824-98-6 m-methoxybenzyl chloride 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 591-31-1 3-methoxy-benzaldehyde 
• 6971-51-3 3-methoxybenzyl alcohol 
• 59647-77-7 bis(3-methoxyphenyl)acetylene 
• 98-51-1 4-tert-butyltoluene 
• 100-84-5 1-methoxy-3-methyl-benzene 
• 75966-32-4 p-tert-butyl-α,α-dibromotoluene 
• 2398-37-0 3-methoxyphenyl bromide 

Downstream Products

• 36707-27-4 1,2-bis(3-methoxyphenyl)ethane 
• 40101-17-5 3,3'-dimethoxybenzil 
• 70709-67-0 3,3'-(ethane-1,2-diyl)diphenol 
• 6266-57-5 1,2-bis(3-methoxyphenyl)ethan-1-one 
• 1454309-28-4 3,3'-(3,3-dibromocyclopropane-1,2-diyl)bis(methoxybenzene) 
• 335152-88-0 (R,R)-(+)-1,2-bis(3-methoxyphenyl)ethane-1,2-diol 
• 10127-54-5 4,5-dimethoxy-phenanthrene 

Relevant articles and documents

Efficient preparation method of symmetric diarylethene compound

The invention belongs to the technical field of fine chemicals and related chemistry, and provides an efficient preparation method of a symmetric diarylethene compound. The method comprises the following steps: with halomethyl-containing aromatic hydrocarbon and derivatives thereof as raw materials, conducting reacting at 100 DEG C for 12 hours in the presence of a catalyst, alkali, additives andan anhydrous organic solvent so as to obtain the corresponding diarylethene compound with symmetry. The method has the beneficial effects that no transition metal reaction exists, reaction conditionsare mild, operation is simple and convenient, the possibility of industrialization is realized, and the diarylethene compound is obtained at high yield; and the diarylethene compound synthesized by using the method can be further functionalized to obtain various compounds, and is applied to development and research of natural products, functional materials and fine chemicals.

Selenenate Anions (PhSeO?) as Organocatalyst: Synthesis of trans-Stilbenes and a PPV Derivative

The selenenate anion (RSeO?) is introduced as an active organocatalyst for the dehydrohalogen coupling of benzyl halides to form trans-stilbenes. It is shown that RSeO? is a more reactive catalyst than the previously reported sulfur analogues (sulfenate anion, RSO?) and selenolate anions (RSe?) in the aforementioned reaction. This catalytic system was also applied to the benzylic-chloromethyl-coupling polymerization (BCCP) of a bis-chloromethyl arene to form ppv (poly(p-phenylene vinylene))-type polymers with high yields, Mn (average molecular weight) up to 13,000 and ? (dispersity) of 1.15. (Figure presented.).

Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

We have developed unprecedented methods for the direct transformation of primary alcohols to alkenes in the presence of hydrazine, and for the synthesis of mixed alkenes by the reaction of alcohols with hydrazones. The reactions are catalyzed by a manganese pincer complex and proceed in absence of added base or hydrogen acceptors, liberating dihydrogen, dinitrogen, and water as the only byproducts. The proposed mechanism, based on preparation of proposed intermediates and control experiments, suggests that the transformation occurs through metal–ligand cooperative N?H activation of a hydrazone intermediate.