6327-85-1Relevant academic research and scientific papers
DINUCLEATING LIGAND OR DINUCLEAR METAL COMPLEX
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Paragraph 0048; 0050-0051, (2021/03/19)
To provide a dinuclear metal complex that can be synthesized simply and easily and has a proper anticancer action.SOLUTION: The present disclosure provides a dinucleating ligand represented by the following formula (I) and a dinuclear metal complex thereof (where each X may be the same or different to represent H, Cl, OMe, or, Me, Y is H, a phenyl group, a substituted carbamoyl group or the like).SELECTED DRAWING: None
DINUCLEATING LIGAND OR DINUCLEAR METAL COMPLEX
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Paragraph 0048; 0062-0063, (2021/03/19)
To provide a dinuclear metal complex that can be synthesized simply and easily and has a proper anticancer action.SOLUTION: The present disclosure provides a dinucleating ligand represented by the following formula (I) and a dinuclear metal complex thereof (where X is H or a substituted carbamoyl group, R1, R2, R3, and R4 independently represent H or a C1-8 linear or branched alkyl group).SELECTED DRAWING: None
Oxidative DNA Cleavage, Formation of μ-1,1-Hydroperoxo Species, and Cytotoxicity of Dicopper(II) Complex Supported by a p-Cresol-Derived Amide-Tether Ligand
Kadoya, Yuki,Fukui, Katsuki,Hata, Machi,Miyano, Risa,Hitomi, Yutaka,Yanagisawa, Sachiko,Kubo, Minoru,Kodera, Masahito
supporting information, p. 14294 - 14298 (2019/10/19)
Metal complexes to promote oxidative DNA cleavage by H2O2 are desirable as anticancer drugs. A dicopper(II) complex of known p-cresol-derived methylene-tether ligand Hbcc [Cu2(bcc)]3+ did not promote DNA cleavag
Synthesis and NMR Spectroscopic Study of the Self-Aggregation of 2-Substituted Benzene-1,3,5-tricarboxamides
Invernizzi, Christian,Dalvit, Claudio,Stoeckli-Evans, Helen,Neier, Reinhard
, p. 5115 - 5127 (2015/08/18)
The self-assembly of N,N′,N′-trialkylbenzene-1,3,5-tricarboxamides (BTAs) 1 or of "crowded" BTAs 11 and 12 lead to supramolecular columnar-stacked structures with attractive material properties. The introduction of three alkoxy groups is reported to reinf
Dinuclear Ag(i) metallamacrocycles of bis-N-heterocyclic carbenes bridged by calixarene fragments: Synthesis, structure and chemosensing behavior
Lin, Cai-Xia,Kong, Xiao-Fei,Li, Qing-Shan,Zhang, Zheng-Zhi,Yuan, Yao-Feng,Xu, Feng-Bo
, p. 6948 - 6962 (2013/09/12)
Dinuclear Ag(i) metallamacrocycles containing bis-N-heterocyclic carbene units and calixarene fragments [{1,1′-R2-3,3′-CH 2{(p-R1-C6H2OMe)CH2} m-bisimidazol-2-ylidene}2/sub
A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields
Law, Ga-Lai,Pham, Tiffany A.,Xu, Jide,Raymond, Kenneth N.
supporting information; experimental part, p. 2371 - 2374 (2012/04/10)
Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex. Copyright
Synthesis of novel benzo-substituted macrocyclic schiff bases containing two triazole rings
Elwahy, Ahmed H. M.,Masaret, Ghada S.
, p. 1475 - 1484 (2008/09/18)
(Chemical Equation Presented) A synthesis of a series of novel macrocyclic Schiff bases containing two triazole rings 10a,b, 11a,b, 34-37 in good yields by heating the appropriate bis-amines 1f, 6a,b, 31 with the corresponding bis-aldehydes 2, 9a,b, 29 in
Synthesis and molecular orbital calculations of some benzo-substituted macrocyclic diamides and their corresponding macrocyclic dithiodiamides
Mohamed, Adel A.,Masaret, Ghada S.,Elwahy, Ahmed H.M.
, p. 4000 - 4010 (2007/10/03)
A new series of benzo-substituted macrocyclic diamides were prepared by nucleophilic reaction of the appropriate dipotassium salts with the corresponding bis(halo) compounds in refluxing DMF. Treatment of the novel macrocyclic diamides with Lawesson's reagent in refluxing toluene led to the formation of the corresponding macrocyclic dithiodiamides in good yields. Molecular orbital calculations were performed at the semi-empirical level AM1 on some of the studied macrocycles. Thermodynamic functions show that the most stable structures in gas phase that have internal amine groups are less in energy than the other ones that have internal carbonyl groups. The solvent polarity does not appreciably affect the stability trend of the three conformers of each compound due to their comparable dipole moments. A complete and thorough survey of proton affinity (PA) and proton detachment energies (PDE) on each of the possible sites has been performed.
AROMATIC TRIAMIDE-LANTHANIDE COMPLEXES
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Page/Page column 73-74, (2008/06/13)
The present invention provides luminescent lanthanide metal chelates comprising a metal ion of the lanthanide series and a complexing agent comprising at least one phthalamidyl moiety. Also provided are probes incorporating the phthalamidyl ligands of the invention and methods utilizing the ligands of the invention and probes comprising the ligands of the invention.
