63272-30-0Relevant academic research and scientific papers
Dioxazole and Dioxetane Intermediates in the Thermal Rearrangement of endo-Peroxides obtained by Dye-sensitized Photo-oxygenation of 2-Alkoxyoxazoles
Graziano, M. Liliana,Iesce, M. Rosaria,Cimminiello, Guido,Scarpati, Rachele,Parrilli, Michaelangelo
, p. 1011 - 1017 (2007/10/02)
Signlet oxygen reacts with 2-alkoxyoxazoles (2c, d) leading to the endo-peroxides (1c, d), which easily rearrange into dioxazoles (3c, d) and dioxetanes (4c, d).Both give carbamates (5c, d) via imino anhydrides (7c, d).When the reaction is carried out in
