6331-99-3

Basic information

• Product Name: 1-ethenyl-2-methylcyclohexanol
• CAS NO: 6331-99-3
• Molecular Formula: C₉H₁₆O
• Molecular Weight: 140.2227
• Mol File: 6331-99-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 193.6°C at 760 mmHg
• Flash Point: 76.1°C
• Density: 0.982g/cm³
• Vapor Pressure: 0.122mmHg at 25°C
• Refractive Index: 1.538
• CAS DataBase Reference: 1-ethenyl-2-methylcyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ethenyl-2-methylcyclohexanol(6331-99-3)
• EPA Substance Registry System: 1-ethenyl-2-methylcyclohexanol(6331-99-3)

Safety Data

• Hazardous Substances Data: 6331-99-3(Hazardous Substances Data)

Usage

Physical state

Colorless liquid

Aroma

Minty

Common uses

Flavor and fragrance ingredient in perfumes, cosmetics, and personal care products

Source

Found in natural sources such as mint oil

Chemical classification

Allyl alcohol derivative

Antimicrobial properties

Potential use as an antimicrobial agent in various applications

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 1826-67-1 vinyl magnesium bromide 
• 15564-30-4 cis-1-Ethinyl-2-methyl-1-cyclohexanol 
• 15564-30-4 cis-1-ethynyl-2-methylcyclohexan-ol 
• 3536-96-7 vinylmagnesium chloride 

Downstream Products

• 87567-29-1 6-methyl-1-vinyl-cyclohexene 
• 7071-16-1 (2-methyl-cyclohexyliden)-acetaldehyde 
• 92886-60-7 2-methyl-2'-(benzoyloxy)ethylidenecyclohexane 
• 67902-68-5 (+/-)-1-((E)-2-acetoxy-ethylidene)-2-methyl-cyclohexane 
• 101568-57-4 2-methyl-1-vinylcyclohexyl acetates 
• 7014-72-4 (+/-)-1-((Ξ)-2-bromo-ethylidene)-2-methyl-cyclohexane 
• 87567-49-5 (E)-1-<2-(neophylsulfonyl)ethylidene>-2-methylcyclohexane 
• 92886-64-1 2-methyl-1-vinylcyclohexyl benzoate 

Relevant articles and documents

Stereoselective Dehydroxyboration of Allylic Alcohols to Access (E)-Allylboronates by a Combination of C-OH Cleavage and Boron Transfer under Iron Catalysis

Iron-catalyzed direct SN2′ dehydroxyboration of allylic alcohols has been developed to access (E)-stereoselective allylboronates. Allylic alcohols with diverse structures and functional groups, especially derived from natural products, underwent smooth transformation. The six-membered ring transition state formed by allylic alcohols and iron-boron intermediate was indicated to be the key component involved in transfer of the boron group, activation of the C-OH bond, and control of the stereoselectivity.

Synthesis of spirocyclic butenolides by ring closing metathesis

Spirocyclic butenolides were efficiently prepared by a ring closing metathesis strategy.

PALLADIUM(II) CATALYZED ALLYLIC REARRANGEMENT: STEREOSELECTIVE SYNTHESIS OF 2-SUBSTITUTED (E)-β-ACETOXY (OR BENZOYLOXY)ETHYLIDENECYCLOHEXANES

Diastereoisomeric mixtures of 2-substituted 1-vinylcyclohexyl acetates (or benzoates) are rearranged stereoselectively to 2-substituted (E)-β-acetoxy (or benzoyloxy)ethylidenecyclohexanes by the catalysis of bis(acetonitrile)palladium(II) chloride.A mechanism related to the stereoselectivity and reactivity is discussed in terms of the conformational requirements in a transition state.