63313-71-3

Basic information

• Product Name: CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE
• CAS NO: 63313-71-3
• Molecular Formula: BF₄*C₁₁H₁₃FeO₄
• Molecular Weight: 0
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis
• Mol File: 63313-71-3.mol

Chemical Properties

• Melting Point: 110 °C (dec.)(lit.)
• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE(CAS DataBase Reference)
• NIST Chemistry Reference: CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE(63313-71-3)
• EPA Substance Registry System: CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE(63313-71-3)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36-36/37
• WGK Germany: 3
• Hazardous Substances Data: 63313-71-3(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE is used as a catalyst for the preparation of β-keto esters via Lewis acid-catalyzed addition of Et diazoacetate to arylaldehydes. Its ability to coordinate with various substrates and facilitate the reaction makes it a valuable catalyst in this process.
Used in Iron Mediated Nitrenoid Transfer:
In this application, CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE acts as a catalyst for iron-mediated nitrenoid transfer, which is an important reaction in the synthesis of various nitrogen-containing compounds.
Used in Lewis Acid Catalyzed Reactions:
CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE is also used as a catalyst in Lewis acid-catalyzed aziridination, cyclopropanation, and insertion reactions with diazo compounds. These reactions are crucial for the synthesis of complex organic molecules and pharmaceuticals.
Used in the Diels-Alder Reaction:
CYCLOPENTADIENYLDICARBONYL(TETRAHYDROFURAN)IRON(II) TETRAFLUOROBORATE is employed as a catalyst in the Diels-Alder reaction of dienes with enones. This reaction is a fundamental step in the synthesis of various natural products and complex organic molecules, and the use of this catalyst enhances the reaction's efficiency and selectivity.

Downstream Products

• 76136-83-9 Fe(C₅H₅)(CO)2(C₆H₅SH)⁽¹⁺⁾*BF₄^(1-)=Fe(C₅H₅)(CO)2(C₆H₅SH)BF₄