63400-32-8Relevant academic research and scientific papers
Catalytic Aerobic Oxidation of Arylhydrazides with Iron Phthalocyanine
Hashimoto, Takuma,Hirose, Daisuke,Taniguchi, Tsuyoshi
, p. 3346 - 3352 (2015)
A convenient method for the synthesis of 2-arylazocarboxylates from 2-arylhydrazinecarboxylates by aerobic oxidation with iron phthalocyanine is described. The reaction is applicable to oxidative activation of 1-acyl-2-phenylhydrazines. Some preliminary experiments suggest Michaelis-Menten kinetics and participation of radical species in the reaction mechanism.
Synthesis of 2-Imino-1,3,4-Thiadiazoles from Hydrazides and Isothiocyanates via Sequential Oxidation and P(NMe2)3-Mediated Annulation Reactions
Huang, Zhengyan,Zhang, Qianqian,Zhao, Qiongli,Yu, Wenquan,Chang, Junbiao
supporting information, p. 4378 - 4382 (2020/06/03)
A P(NMe2)3-mediated annulation reaction of N-Acyldiazenes with isothiocyanates, producing 2-imino-1,3,4-Thiadiazoles, is reported. This reaction proceeds well with crude N-Acyldiazenes derived from the oxidation of hydrazides by iodi
