6344-52-1Relevant articles and documents
REACTIONS OF TRIALKYL PHOSPHITES WITH KETONES IN THE PRESENCE OF PROTON-DONOR REACTANTS. I. REACTION OF TRIMETHYL PHOSPHITE WITH FLUORENONE IN THE PRESENCE OF ACETIC ACID
Fuzhenkova, A. V.,Tyryshkin, N. I.
, p. 76 - 80 (2007/10/02)
Trimethyl phosphite reacts with fluorenone in the presence of acetic acid to give dimethyl 9-fluorenyl phosphate, 9-fluorenyl acetate, and hydroxyfluorene.The data obtained indicate that ketones react with trialkyl phosphites in the presence of carboxylic acids to give phosphonates and acetonates with a geminal position of the proton and the corresponding group, and also products of ketone reduction.