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Prop-2-enyl 2-phenylbutanoate, also known as cinnamate of allyl, is an organic compound with the chemical formula C12H14O2. It is a colorless to pale yellow liquid with a fruity, balsamic, and slightly green odor. This ester is formed by the reaction of prop-2-enol (allyl alcohol) and 2-phenylbutanoic acid (cinnamic acid). Prop-2-enyl 2-phenylbutanoate is widely used in the fragrance and flavor industry, particularly in the creation of floral, fruity, and green notes. It can be found in various applications, such as perfumes, cosmetics, and food products, where it adds a pleasant aroma and taste. The compound is also known for its potential use in the synthesis of other organic compounds and as a chemical intermediate in various industrial processes.

6345-86-4

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6345-86-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6345-86-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,3,4 and 5 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6345-86:
(6*6)+(5*3)+(4*4)+(3*5)+(2*8)+(1*6)=104
104 % 10 = 4
So 6345-86-4 is a valid CAS Registry Number.
InChI:InChI=1/C13H16O2/c1-3-10-15-13(14)12(4-2)11-8-6-5-7-9-11/h3,5-9,12H,1,4,10H2,2H3

6345-86-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name prop-2-enyl 2-phenylbutanoate

1.2 Other means of identification

Product number -
Other names prop-2-en-1-yl 2-phenylbutanoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
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More Details:6345-86-4 SDS

6345-86-4Downstream Products

6345-86-4Relevant academic research and scientific papers

Chemo- and Enantioselective Pd/B Hybrid Catalysis for the Construction of Acyclic Quaternary Carbons: Migratory Allylation of O-Allyl Esters to α- C-Allyl Carboxylic Acids

Fujita, Taiki,Yamamoto, Tomohiro,Morita, Yuya,Chen, Hongyu,Shimizu, Yohei,Kanai, Motomu

supporting information, p. 5899 - 5903 (2018/05/14)

We describe herein the asymmetric synthesis of α-allyl carboxylic acids containing an α-quaternary stereocenter by a chiral hybrid catalyst system comprising palladium and boron complexes. The reaction proceeded through palladium-catalyzed ionization of α,α-disubstituted O-allyl esters for the generation of chiral π-allyl palladium complex as an electrophile, boron-catalyzed enolization of the carboxylate part for the generation of chiral α,α-disubstituted carboxylic acid-derived enolates as a nucleophile, and enantioselective coupling between the thus-generated nucleophile and electrophile. Proper combinations of chiral ligands for the boron and palladium catalysts were crucial. The reaction proceeded chemoselectively at the α-position of the carboxylic acid group.

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