634599-85-2Relevant articles and documents
Synthesis and characterization of mononuclear and tetranuclear palladium(II) complexes with 2-(phenylmethyleneamino)benzenethiolate
Kawamoto, Tatsuya,Nagasawa, Isoroku,Kushi, Yoshihiko,Konno, Takumi
, p. 217 - 220 (2003)
Two palladium(II) complexes, [Pd(Hphbt-N,S)2] (1; Hphbt=2-(phenylmethyleneamino)benzenethiolate) and [Pd4(phbt-C,N,S)4] (2), were newly prepared. X-ray and 1H NMR studies indicated the presence of Pd?H-C interaction in the mononuclear 1, which is assumed to play an important role in the cyclometalation reaction leading to the tetranuclear structure in 2.