63592-80-3

Upstream product

• 74213-85-7 (4aR,6S,8S,8aS)-8-Benzyloxy-6-methoxy-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 74213-88-0 Toluene-4-sulfonic acid (2R,3S,4S,6S)-4-benzyloxy-2-cyanomethyl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 74213-90-4 (3aR,5S,7S,7aR)-7-Benzyloxy-5-methoxy-octahydro-pyrano[3,2-b]pyrrole 
• 74213-93-7 [(S)-1-((3aR,7S,7aR)-7-Benzyloxy-5-oxo-hexahydro-pyrano[3,2-b]pyrrole-1-carbonyl)-2-methyl-propyl]-carbamic acid benzyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF DETOXININOLACTONE DERIVATIVES AND THE REVISED ABSOLUTE STEREOCHEMISTRY OF DETOXININE

A stereocpecific synthesis of acetyl-L-valyl-detoxininolactone has been performed and the absolute stereochemistry of detoxinine has been revised to (2S,3R,1'S)-2-(2'-carboxy-1'-hydroxyethyl)-3-hydroxypyrrolidine.