636596-60-6

Upstream product

• 4039-82-1 Benzyl propargyl ether 
• 109170-83-4 (S)-2-<(triethylsilyl)oxy>-2-propanal 
• 109170-82-3 α-(triethylsiloxy)propanoic acid ethyl ester 

Downstream Products

• 335164-86-8 ((4R,5S)-4-Di-tert-butyl-silanyloxy-5-triethylsilanyloxy-hex-2-ynyloxymethyl)-benzene 
• 335164-87-9 (2S,3R)-3-[[bis(1,1-dimethylethyl)silyl]oxy]-6-(phenylmethoxy)-4-hexyn-2-ol 
• 335164-89-1 (3α,3aβ,6β,6aβ)-2,2-bis(1,1-dimethylethyl)tetrahydro-6-methyl-3-[(phenylmethoxy)methyl]furo[3,4-d]-1,2-oxasilol-4(2H)-one 
• 335164-88-0 (2S,3R)-3-[[bis(1,1-dimethylethyl)silyl]oxy]-6-(phenylmethoxy)-4-hexyn-2-ol 

Relevant academic research and scientific papers

Systematic Construction of a Monotetrahydrofuran-Ring Library in Annonaceous Acetogenins by Asymmetric Alkynylation and Stereodivergent Tetrahydrofuran-Ring Formation

All eight diastereoisomers of the monotetrahydrofuran-ring cores of annonaceous acetogenins have been synthesized through utilization of asymmetric alkynylation and stereodivergent one-pot tetrahydrofuran-ring formation. In all cases, the asymmetric alkyn

Preparation of tetrahydrofuran, γ-lactone, chromanol and pyrrolidine systems by sequential 5-exo-digonal radical cyclization, 1,5-hydrogen transfer from silicon, and 5-endo-trigonal cyclization

Sequential 5-exo-digonal radical closure, intramolecular 1,5-hydrogen transfer from silicon to carbon, and 5-endo-trigonal closure of the resulting silicon-centred radicals are used to make five- and six-membered heterocycles containing oxygen or nitrogen.