636609-69-3

Basic information

• Product Name: Rh(CH₃P(CPS(C₆H₅)2CC₆H₅)2CH)(P(C₆H₅)3)(CO)
• CAS NO: 636609-69-3
• Molecular Weight: 1088.99
• Mol File: 636609-69-3.mol

Chemical Properties

• CAS DataBase Reference: Rh(CH₃P(CPS(C₆H₅)2CC₆H₅)2CH)(P(C₆H₅)3)(CO)(CAS DataBase Reference)
• NIST Chemistry Reference: Rh(CH₃P(CPS(C₆H₅)2CC₆H₅)2CH)(P(C₆H₅)3)(CO)(636609-69-3)
• EPA Substance Registry System: Rh(CH₃P(CPS(C₆H₅)2CC₆H₅)2CH)(P(C₆H₅)3)(CO)(636609-69-3)

Safety Data

• Hazardous Substances Data: 636609-69-3(Hazardous Substances Data)

Upstream product

• 636609-67-1 [Rh(I)(1-methyl-1-P-2,6-bis(diphenylphosphinosulfide)-3,5-(bisphenyl)-phosphine)(PPh₃)] 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

Planar discrimination in an SPS-based rhodium(I) complex

This work describes the reactivity of the SPS-type pincer-based RhI complex 4 toward CO, O2, CO2, Cs2, and SO2 to afford the corresponding RhI or RhIII adducts. The SPS ligand is able to adopt a facial coordination mode in these trigonal-bipyramidal complexes. Differentiation of the two faces of the square-planar RhI complex 4 could be rationalized by a mechanical effect due to the rigidity of the central phosphinine backbone.