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Tris-(2,6-dideuterio-phenyl)-phosphane, also known as tris(2,6-di-deuteriophenyl)phosphine, is a phosphorus-containing organic compound with the chemical formula C18D6H3P. It is a deuterated analog of tris(2,6-diphenyl)phosphane, where the hydrogen atoms at the 2 and 6 positions of the phenyl rings are replaced with deuterium atoms. This modification enhances the stability and solubility of the compound in various solvents, making it useful in chemical reactions and as a ligand in coordination chemistry. The deuteration also provides a means to study the effects of isotopic substitution on reaction kinetics and mechanisms. Tris-(2,6-dideuterio-phenyl)-phosphane is a valuable tool in synthetic chemistry, particularly in the preparation of deuterated compounds and in applications where the reduced isotopic mass of deuterium can provide insights into reaction pathways.

63683-54-5

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63683-54-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 63683-54-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,3,6,8 and 3 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 63683-54:
(7*6)+(6*3)+(5*6)+(4*8)+(3*3)+(2*5)+(1*4)=145
145 % 10 = 5
So 63683-54-5 is a valid CAS Registry Number.

63683-54-5Upstream product

63683-54-5Downstream Products

63683-54-5Relevant academic research and scientific papers

Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

Bresó-Femenia, Emma,Godard, Cyril,Claver, Carmen,Chaudret, Bruno,Castillón, Sergio

supporting information, p. 16342 - 16345 (2015/11/17)

Phenyl rings in phenyl- or phenyl-alkylphosphines are selectively deuterated at the ortho position using Ru/PVP nanoparticles, while are fully reduced in the case of arylphosphine oxide derivatives and do not react in the case of arylphosphite. This different behavior provides information about the coordination mode of each ligand.

Platinum catalyzed H-D exchange reaction of various aromatic compounds under hydrothermal condition

Yamamoto, Mitsuru,Oshima, Koichiro,Matsubara, Seijiro

, p. 353 - 359 (2007/10/03)

Various aromatic compounds were treated with deuterium oxide under hydrothermal conditions in the presence of a catalytic amount of platinum (IV) oxide. An efficient H-D exchange reaction was observed, which gave various deterium labeled aromatic compounds.

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