637009-12-2

Basic information

• Product Name: 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1-triisopropylsilanyl-1H-pyrrole
• Synonyms: 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1-triisopropylsilanyl-1H-pyrrole
• CAS NO: 637009-12-2
• Molecular Weight: 634.019
• Mol File: 637009-12-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1-triisopropylsilanyl-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1-triisopropylsilanyl-1H-pyrrole(637009-12-2)
• EPA Substance Registry System: 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1-triisopropylsilanyl-1H-pyrrole(637009-12-2)

Safety Data

• Hazardous Substances Data: 637009-12-2(Hazardous Substances Data)

Upstream product

• 96690-02-7 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose 
• 87630-35-1 N-triisopropylsilylpyrrole 
• 478367-12-3 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-ribofuranosyl trichloroacetamidate 

Downstream Products

• 637009-15-5 3-[6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-1H-pyrrole 

Relevant articles and documents

Syntheses of showdomycin and its anomer using N-(triisopropylsilyl)pyrrole as a synthetic equivalent for the maleimide C3-anion

Showdomycin (1) and its anomer (2) have been prepared in four steps from readily available trichloroacetimidate 9. The key step involves reaction of the last compound with the title pyrrole 3 so as to form a chromatographically separable mixture of the pyrrole C-glycosides 10 and 11. These pyrroles are desilylated then oxidized to the corresponding maleimides using PCC.