637024-33-0Relevant academic research and scientific papers
Synthesis and Cycloaromatization of a Cyclic Enyne-Allene Prodrug
Bekele, Tefsit,Brunette, Steven R.,Lipton, Mark A.
, p. 8471 - 8479 (2003)
A simple and stable cyclic enediynone (4) has been synthesized using an intramolecular Nozaki-Hiyama-Kishi cyclization as the key step. Reaction with a thiolate nucleophile led to rapid cycloaromatization of 4. Trapping experiments using 1,4-cyclohexadien
