637025-08-2Relevant academic research and scientific papers
Stereospecific Pd(0)-Catalyzed Arylation of an Allylic Hydroxy Phosphonate Derivative: Formal Synthesis of (S)-(+)-ar-Turmerone
Rowe, Bradley J.,Spilling, Christopher D.
, p. 9502 - 9505 (2003)
Reaction of the (1S)-allylic hydroxy phosphonate 1(S) with methyl chloroformate in pyridine yields the corresponding carbonate 3(S). The carbonate 3(S) undergoes a palladium-catalyzed arylation with p-tolyl tributylstannane to give both the 1E and 1Z viny
