63703-15-1Relevant academic research and scientific papers
SYNTHESIS AND REACTIONS OF THE OXIDES OF HEXAFLUOROPROPYLENE TRIMERS
Zapevalov, A. Ya.,Filyakova, T. I.,Peschanskii, N. V.,Kodess, M. I.,Kolenko, I. P.
, p. 1933 - 1938 (2007/10/02)
By the oxidation of the hexafluoropropylene trimers with an aqueous solution of sodium hypochlorite in the presence of acetonitrile the following α-oxides were obtained: 2,3-Epoxyperfluoro-3-isopropyl-4-methylpentane and 2,3-epoxyperofluoro-3-ethyl-2,4-dimethylpentane.According to the 19F NMR data, the epoxidation takes place stereoselectively with the formation of only one conformer of the α-oxide in each case.The determining effect of the steric factors on the reactivity of the oxides of hexafluoropropylene trimers in reaction with nucleophiles was demonstrated.
