63703-16-2 Usage
Uses
Used in Organic Synthesis:
6H-Perfluorohexyl iodide is used as a starting material in organic synthesis, particularly for the preparation of fluorinated compounds. Its high reactivity due to the presence of the iodine atom makes it useful in the production of various fluorinated materials for industrial and research purposes.
Used in Material Science:
6H-Perfluorohexyl iodide is used as a component in the development of materials with specific properties. Its water-repellent and low surface energy characteristics make it potentially useful in applications such as water and oil repellent coatings, contributing to the advancement of material science and technology.
Used in Industrial Applications:
In the industrial sector, 6H-Perfluorohexyl iodide is utilized in the production of various fluorinated materials that have specific applications in different industries. Its versatility and chemical properties make it a valuable compound for creating innovative and specialized products.
Used in Research and Development:
6H-Perfluorohexyl iodide plays a significant role in research and development, where it is employed to explore new chemical reactions and synthesize novel fluorinated compounds. Its unique properties and reactivity contribute to the discovery of new materials and applications in the scientific community.
Check Digit Verification of cas no
The CAS Registry Mumber 63703-16-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,3,7,0 and 3 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 63703-16:
(7*6)+(6*3)+(5*7)+(4*0)+(3*3)+(2*1)+(1*6)=112
112 % 10 = 2
So 63703-16-2 is a valid CAS Registry Number.
InChI:InChI=1/C6HF12I/c7-1(8)2(9,10)3(11,12)4(13,14)5(15,16)6(17,18)19/h1H
63703-16-2Relevant academic research and scientific papers
Complexation and Photoinduced Electron-transfer Reaction between Perfluoroalkyl Iodides and N,N,N',N'-Tetramethylphenylene-1,4-diamine, Anilines and Piperazines
Chen, Qing-Yun,Li, Zhan-Ting,Zhou, Cheng-Min
, p. 2457 - 2462 (2007/10/02)
Treatment of tetrafluoro-1,2-diiodoethane 1a or dodecafluoro-1,6-diiodohexane 1b with N,N,N',N'-tetramethylphenylene-1,4-diamine 2 gave 1 + 1 solid complexes 3a or 3b in high yields.Complex 3a decomposed to give tetrafluoroethylene, iodine and 2 when irradiated with UV or heated.Complex 3b was converted into 6H-dodecafluorohexyl-N,N,N',N'-tetramethylphenylene-1,4-diamine 4 when irradiated with UV.On treatment of 1a and 1b with piperazine 6a and N,N'-dimethylpiperazine 6b, 1 + 1 solid complexes 7 were similarly obtained.However, heating or irradiating 7 gave no perfluoroalkylated products.Irradiating a mixture of 2 or anilines 13 and perfluoroalkyl iodides 10 in dimethylformamide also gave perfluoroalkylated products.The photoinduced electron transfer reaction involved radical cation 2*+ as a reactive intermediate which was detected by EPR techniques.
PERFLUOROALKYLATION OF 2-MERCAPTOBENZOTHIAZOLE AND ITS ANALOGUES WITH PERFLUOROALKYL IODIDES BY AN SRN1 REACTION
Chen, Qing-Yun,Chen, Mei-Jin
, p. 21 - 32 (2007/10/02)
The thiolates, generated in situ by the reaction of 2-mercaptobenzothiazole (1) and its analogues (2) and (3) with sodium hydride, react under UV irradiation with perfluoroalkyl iodides (4)-(8) to give the corresponding heteroaromatic perfluoroalkyl sulfides (9)-(18) in 50-98percent yields.The fact that the UV irradiation increases the conversion of perfluoroalkyl iodides and that the radical scavenger di-tert-butylnitroxide suppresses the reaction demonstrates that the reaction proceeds via an SRN1 mechanism.
