637041-30-6Relevant articles and documents
Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride: The effects of substituents on the cleavage of the cyclopropane ring
Kirihara, Masayuki,Kakuda, Hiroko,Tsunooka, Makoto,Shimajiri, Akihiro,Takuwa, Tomofumi,Hatano, Akihiko
, p. 8513 - 8518 (2007/10/03)
The reaction of tertiary cyclopropanol silyl ethers with diethylaminosulfur trifluoride usually causes ring opening to produce allylic fluorides. However, cyclopropyl silyl ethers bearing a strong electron-donating substituent at C1 or an electron-withdra