63710-87-2Relevant academic research and scientific papers
Substituent Effect on the Spin-trapping Reactions of Substituted N-Benzylidene-t-butylamine N-oxides
Murofushi, Katsumi,Abe, Kazuhisa,Hirota, Minoru
, p. 1829 - 1834 (2007/10/02)
Relative rates of the reactions of substituted N-benzylidene-t-butylamine N-oxides with substituted phenyl free radicals have been determined by e.s.r. spectroscopic analyses of the products from competitive addition reactions.The substituent effect was interpreted in terms of a reaction mechanism involving an electron-transfer interaction between the reactants.The results are in accord with semiempirical MO calculations.
