6373-93-9Relevant academic research and scientific papers
Some heterocyclic azo dyes derived from thiazolyl derivatives; Synthesis; substituent effects and solvatochromic studies
Yazdanbakhsh,Mohammadi,Abbasnia
experimental part, p. 1084 - 1087 (2011/01/11)
A series of azo disperse dyes were synthesized by coupling reaction of N,N-diethylaniline, 2-anilinoethanol and N-phenyl-2,2′-iminodiethanol with diazotized aminothiazolyl derivatives as diazo components. These dyes have been prepared in good yields, and were characterized by UV-Vis, FT-IR and 1H NMR spectroscopic techniques. The effects of solvent polarity and various pH on dyes in the visible absorption spectra were evaluated. All dyes exhibit an excellent correlation coefficient (r > 0.92) for the linear solvation energy relationship with π* values calculated by Kamlet et al. The influence of the pH on the dyes with electron-donating group implied that these dyes exist in acid-base equilibrium in acidic environment. The effect of substituents of both coupler and diazo component on the color of dyes was investigated as well.
CATIONIC DYES
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Page/Page column 29, (2008/12/07)
Disclosed are dyes of Formula (I) wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine,perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; Q is C 1-C 30alkylene, -C 2-C 12alkenylene, C 5-C10arylene-, C 5-C 10cycloalkylene-or -C 1- C 10alkylene(C5-C10arylene)-which may be interrupted and/or terminated at one or both ends by one or more than one -O-, -S-, -N=, -N(R 1)-, SO2, -(CH 2CH 2-O) 1-5-, -(CH 2CH 2CH 2-O) 1-5-, -C(O)-, -C(O)-C1-C12alkenylene, -C(O)O-, -OCO-, AN+ R 1 R 2, -CON(R 1)-, -C(NR1R2) 2-, -(R1)NC(O)-, -CSR1-or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic) bivalent radical optionally comprising at least one heteroatom; -O-; -S-; -N(R1)-; SO2; -(CH2CH2-O) 1-5-; -C(O)-; -C(O)-C1-C12alkenylene; -C(O)O-, -OCO-;B N+ R 1 R 2; -CON(R1)-; -C(NR1R 2) 2-; -(R1)NC(O)-; CSR1; saturated or unsaturated, fused or non-fused aromatic or nonaro- matic bivalent radical optionally comprising at least one heteroatom; which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, -C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or D+; R1and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C1-C14hydroxyalkyl; C1-C14 aminoalkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1- C10alkyl; or C 5-C 10alkyl(C5-C10aryl).
