637362-46-0

Upstream product

• 637362-45-9 (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane 
• 74269-63-9 (1-Benzyloxymethyl-cyclohexa-2,5-dienyl)-methanol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 637362-52-8 3a-benzenesulfonyl-6a-(tert-butyl-dimethyl-silanyloxymethyl)-1,3a,3b,4,6a,6b-hexahydro-2H-cyclopropa[de]naphthalen-3-one 
• 637362-51-7 1-benzenesulfonyl-4-[1-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-1-diazo-butan-2-one 
• 637362-50-6 1-benzenesulfonyl-4-[1-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-butan-2-one 
• 637362-47-1 1-[(tert-butyldimethylsilyloxy)methyl]cyclohexa-2,5-dienecarbaldehyde 

Relevant academic research and scientific papers

An unexpected Prins desymmetrisation reaction driven by silyl migration

Prins desymmetrisation reactions of cyclohexa-1,4-diene derivatives have been investigated as a route to the core of the cladiellin diterpenes. During the course of this work, we observed the formation of a partially-reduced benzofuran 18, which is clearl

Enantioselective intramolecular cyclopropanation of α-diazo-β- keto sulfones: Asymmetric synthesis of bicyclo[4.1.0]heptanes and tricyclo[4.4.0.0]decenes

Catalytic asymmetric synthesis of some new chiral building blocks useful for natural product synthesis is described. The intramolecular cyclopropanation (IMCP) reaction of α-diazo-β-keto sulfones affording bicyclo[4.1.0]heptanes such as 9a-d is found to p