637362-48-2

Upstream product

• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 637362-47-1 1-[(tert-butyldimethylsilyloxy)methyl]cyclohexa-2,5-dienecarbaldehyde 
• 637362-45-9 (1-benzyloxymethyl-cyclohexa-2,5-dienylmethoxy)-tert-butyl-dimethyl-silane 
• 74269-63-9 (1-Benzyloxymethyl-cyclohexa-2,5-dienyl)-methanol 

Downstream Products

• 637362-49-3 3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-propionic acid methyl ester 
• 637362-52-8 3a-benzenesulfonyl-6a-(tert-butyl-dimethyl-silanyloxymethyl)-1,3a,3b,4,6a,6b-hexahydro-2H-cyclopropa[de]naphthalen-3-one 

Relevant academic research and scientific papers

Enantioselective intramolecular cyclopropanation of α-diazo-β- keto sulfones: Asymmetric synthesis of bicyclo[4.1.0]heptanes and tricyclo[4.4.0.0]decenes

Catalytic asymmetric synthesis of some new chiral building blocks useful for natural product synthesis is described. The intramolecular cyclopropanation (IMCP) reaction of α-diazo-β-keto sulfones affording bicyclo[4.1.0]heptanes such as 9a-d is found to p