63756-98-9Relevant academic research and scientific papers
One-Pot Synthesis of Indoles and Pyrazoles via Pd-Catalyzed Couplings/Cyclizations Enabled by Aqueous Micellar Catalysis
Akporji, Nnamdi,Braga, Felipe C.,Gabriel, Christopher M.,Landstrom, Evan B.,Lee, Nicholas R.,Lipshutz, Bruce H.
supporting information, (2020/09/02)
An effective one-pot synthesis of either indoles or pyrazoles can be achieved via Pd-catalyzed aminations followed by subsequent cyclizations facilitated by aqueous micellar catalysis. This new technology includes efficient couplings with low loadings of palladium, a more stable source of the required hydrazine moiety, greater atom economy for the initial coupling, and reduced reaction temperatures, all leading to environmentally responsible processes.
ADDITION OF ARYLMETALLICS TO AZODICARBOXYLATES: A NOVEL SYNTHESIS OF ARYLHYDRAZINES BY AROMATIC HYDRAZINATION
Demers, James P.,Klaubert, Dieter H.
, p. 4933 - 4934 (2007/10/02)
Aryllithiums and arylmagnesium bromides add to the N=N bond of di-t-butyl azodicarboxylate, and subsequent acid deprotection provides the arylhydrazine.
Phenyl-1,2,3,4-tetrahydrocarbazoles and use thereof
-
, (2008/06/13)
This application relates to phenyl-substituted 1,2,3,4-tetrahydrocarbazoles and to their use as anti-depressant agents useful in the treatment of mental depression of either endogenous or reactive nature.
