63796-18-9Relevant academic research and scientific papers
Oxidation of Mixtures of Thioureas: Part VII - Formation of 4-Alkyl-5-alkylimino-3-amino-4,5-dihydro-1,2,4-thiadiazoles
Indukumari, P. V.,Joshua, C. P.
, p. 667 - 671 (2007/10/02)
Oxidation of acidic ethanolic solutions of binary mixtures of 1,3-diethyl, 1,3-di-n-propyl, 1,3-diisopropyl, 1,3-di-n-butyl, 1,3-dibenzyl, 1-benzyl-3-methyl, 1-benzyl-3-ethyl, 1-benzyl-3-n-propyl, 1-benzyl-3-n-butyl, 1-n-butyl-3-n-propyl-thioureas with thiourea has been found to yield the related 4-alkyl-5-alkylimino-3-amino-4,5-dihydro-1,2,4-thiadiazoles (3).The mechanism of formation of these thiadiazoles has been discussed.One of the intermediates, viz. bis(formamidino)sulphide salt has been alternatively prepared and its further reactions studied.
