63823-52-9Relevant academic research and scientific papers
Aggregative activation and carbanion chemistry: Complex base deprotonation and directed functionalisation of dithioacetals
Gros, Philippe,Hansen, Philippe,Caubere, Paul
, p. 15147 - 15156 (2007/10/03)
Bis(phenylthio)methane and [1,3]-dithiane were efficiently deprotonated by the NaNH2-Et(OCH2CH2)2-ONa complex base. A marked behaviour difference was observed between the sodium carbanion of [1,3]-dithiane and the corresponding lithio-derivative. A 'radicaloid' mechanism is proposed to explain the results observed.
A Positive Halogen Mediated Ring-Opening Reaction of 2-(α-Phenylthiobenzyl)cycloalkanol Derivatives
Yasumura, Masateru,Takaki, Ken,Tamura, Takao,Negoro, Kenji
, p. 317 - 318 (2007/10/02)
A new ring-opening reaction of the title cycloalkanols (1 and 3) takes place upon treatment with N-chloro-succinimide and triethylamine to give ω-oxo α,β-unsaturated sulfides (2) in fairly good yields
