63846-85-5Relevant academic research and scientific papers
Nickel(0)-Catalyzed Cross Coupling Reactions of (Tricyclo2,7>hept-1-yl)magnesium Bromide and Related Grignard Reagents with Aryl, Vinyl, and Alkynyl Halides
Kottirsch, Georg,Szeimies, Guenter
, p. 1495 - 1505 (2007/10/02)
(Tricyclo2,7>hept-1-yl)magnesium bromide (1c) and similar Grignard reagents like 2c, 3a-d, and 4 were cross-coupled with a series of aryl, vinyl, and alkynyl chlorides or bromides in the presence of approximately 1percent of nickel dichloride (NidppeCl2) leading to bridgehead-substituted aryl-, vinyl-, and alkynylbicyclobutanes in varying yields.
