6386-72-7

Upstream product

• 1522-03-8 tetra-trans-propenyl stannane 
• 591-51-5 phenyllithium 
• 60-29-7 diethyl ether 
• 590-15-8 trans-2-propenyl bromide 
• 1522-03-8 tetra-cis-propenyl stannane 

Downstream Products

• 6052-56-8 1,1-diphenyl-2-buten-1-ol 
• 52755-38-1 (Z)-1-phenyl-but-2-en-1-ol 
• 433711-83-2 {(2S)-methoxy-(1R)-[1-(4-methoxybenzyl)-5-oxo-(3S)-Z-propenylpyrrolidin-(2R)-yl]-(2S)-methylpentyl}-carbamic acid tert-butyl ester 
• 433711-89-8 {(2S)-methoxy-(1R)-[1-(2,4-dimethoxy)-benzyl-5-oxo-(3S)-Z-propenylpyrrolidin-(2R)-yl]-(2S)-methylpentyl}-carbamic acid tert-butyl ester 
• 386253-26-5 (S)-1-(benzyloxy)-3-methyl-N-(phenyl((R)-2-((Z)-prop-1-enyl)pyridin-1(2H)-yl)methylene)butan-2-amine 
• 6052-56-8 1,1-diphenyl-2-buten-1-ol 
• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 
• 1569-50-2 3-penten-2-ol 
• 83333-75-9 (E)-2-phenylpent-3-en-2-ol 
• 207302-95-2 (3R,4R,5R,6S)-5-Bromo-6-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methoxy-4-methyl-tetrahydro-pyran-2-one 
• 207302-96-3 (3R,4S,5S)-5-{[(1S)-3,3-diethyl-2,4-dioxolanyl]bromomethyl}-3-methoxy-4-methyloxolan-2-one 
• 120254-60-6 O-Benzyl-N-((E)-1-methyl-but-2-enyl)-hydroxylamine 
• 108897-21-8 1-(1-phenyl-but-2ξ-enyl)-pyrrolidine 
• 41905-69-5 ((Z)-1-Methoxy-but-1-enyl)-benzene 

Relevant academic research and scientific papers

Ligand-Free Iron-Catalyzed Carbon(sp2)-Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesis of diversified diene derivatives.

Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji–Trost Reaction

Vinyl chromium(0) Fischer carbene complexes were employed as the source of π-allylic palladium species for catalytic [3+3] annulation under palladium catalysis. Mechanistically, this transformation is proposed to involve carbene migratory insertion and intramolecular Tsuji–Trost reaction as the key steps. Substituted six-membered heterocyclic flavonones and quinolines are obtained, depending on the nucleophilic functional group on the coupling partners.