639799-27-2

Upstream product

• 639079-51-9 (-)-4,5-di-O-acetyl-3,6-dideoxy-3,6-diazido-myo-inositol 
• 169529-92-4 (+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 140696-30-6 (1R,2S,3R,6R)-2-bromo-7-oxabicyclo[4.1.0]hept-4-en-3-ol 
• 639079-49-5 (1S,2R,3R,4S)-1,4-diazidoconduritol B 
• 639079-50-8 (1S,2R,3R,4S)-2,3-di-O-acetyl-1,4-diazidoconduritol B 

Relevant academic research and scientific papers

Stereoselective synthesis of several azido/amino- and diazido/diamino-myo-inositols and their phosphates from p-benzoquinone

A practical route is described for the preparation of azido-myo-inositols, amino-myo-inositols and azido-conduritol B derivatives. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol B derivative. Selective introduction of nitrogen-containing functional groups in four of the six possible positions in the cyclitol moiety is followed by further functionalization to yield the target compounds.