6401-01-0

Basic information

• Product Name: 1H,1H-HEPTAFLUOROBUTYL TRIFLATE
• Synonyms: 2,2,3,3,4,4,4-HEPTAFLUOROBUTYL TRIFLUOROMETHANESULFONATE;2,2,3,3,4,4,4-HEPTAFLUOROBUTYL TRIFLUOROMETHANESULPHONATE;1H,1H-HEPTAFLUOROBUTYL TRIFLATE;1H,1H-HEPTAFLUOROBUTYL TRIFLUOROMETHANESULFONATE;1H,1H-Heptafluorobutyl trifluoromethanesulphonate;1H,1H-Heptafluorobutyl trifluoromethanesulphonate 97%;1H,1H-Heptafluorobutyltrifluoromethanesulphonate97%
• CAS NO: 6401-01-0
• Molecular Formula: C₅H₂F₁₀O₃S
• Molecular Weight: 332.12
• Mol File: 6401-01-0.mol

Chemical Properties

• Boiling Point: 118-120/732mm
• Appearance: /
• Refractive Index: 1.302
• CAS DataBase Reference: 1H,1H-HEPTAFLUOROBUTYL TRIFLATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1H,1H-HEPTAFLUOROBUTYL TRIFLATE(6401-01-0)
• EPA Substance Registry System: 1H,1H-HEPTAFLUOROBUTYL TRIFLATE(6401-01-0)

Safety Data

• Hazard Codes: C,T
• HazardClass: TOXIC, CORROSIVE
• Hazardous Substances Data: 6401-01-0(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
1H,1H-Heptafluorobutyl triflate is used as a catalyst and reagent for stabilizing carbon cations in the formation of carbon-carbon and carbon-heteroatom bonds, enhancing the efficiency and selectivity of organic synthesis reactions.
Used in Pharmaceutical Industry:
1H,1H-Heptafluorobutyl triflate is used as a catalyst in the synthesis of complex organic molecules for pharmaceutical applications, leveraging its unique properties to improve the efficiency and selectivity of chemical reactions.
Used in Agrochemical Industry:
1H,1H-Heptafluorobutyl triflate is employed as a strong acid catalyst in the synthesis of agrochemical compounds, promoting selectivity and efficiency in the formation of desired products.

Upstream product

• 375-01-9 2,2,3,3,4,4,4-heptafluorobutanol 
• 335-05-7 Trifluoromethanesulfonyl fluoride 
• 421-83-0 trifluoromethane sulfonyl chloride 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 121-44-8 triethylamine 

Downstream Products

• 109230-68-4 4-nitro-1-(2,2,3,3,4,4,4-heptafluorobutoxy)benzene 
• 129560-95-8 4-(1,1-dihydroperfluorobutyloxy)phenol 
• 129590-24-5 4-(1,1-dihydroperfluorobutyloxy)benzoic acid 

Relevant articles and documents

Synthesis and characterization of light-fluorous NHC-ligands and their palladium complexes

Light-fluorous ponytails containing perfluoro-n-propyl, perfluoro-n-butyl and perfluoro-t-butoxy groups were used to synthesize light-fluorous α-olefins, branched dialkyl iodides, alkyl triflates, alkyl imidazoles, and dialkyl imidazolium salts. The latte

AMIDINE COMPOUNDS AND USE THEREOF FOR PLANT DISEASE CONTROL

An amidine compound represented by formula (1): wherein R1 represent a C1-C11 fluoroalkyl group, a C3-C11 fluoroalkenyl group or a C3-C11 fluoroalkynyl group; R2 represent a C1-C3 alkyl group; R3 represent a C1-C3 alkyl group; R4 represent a C3-C6 cycloalkyl group or a C1-C6 alkyl group optionally having one or more halogens and R5 represent a C3-C6 cycloalkyl group or a C1-C6 alkyl group optionally having one or more halogens, said compound having excellent plant disease controlling effect.

NITRILE COMPOUND AND ITS USE IN PEST CONTROL

The present invention provides a nitrile compound represented by the formula (I): wherein R represents C1-C4 fluoroalkyl, Q represents halogen, C1-C11 alkyl optionally substituted with halogen, C2-C6 alkenyl group optionally substituted with halogen, C2-C6 alkynyl optionally substituted with halogen, C3-C7 cycloalkyl optionally substituted with halogen or (C3-C7 cycloalkyl optionally substituted with halogen)C1-C4 alkyl, which has excellent control effect against pests.

Various synthetic approaches to fluoroalkyl p-nitrophenyl ethers

Homologous 1H,1H-perfluoroalkyl p-nitrophenyl ethers (alkyl = C2-C8) were synthesized using different methods. The results are discussed in context with contradictory comments of the literature. The fluoroalkoxylation of p-chloronitrobenzene occurs in only one step, but it is limited to small fluoroalkyl groups. The fluoroalkylation of p-nitrophenol via sulphonic acid esters is a better synthetic route. Differences in reactivity and yield between tosylates, mesylates and inflates are found and discussed. The preferred synthesis includes the use of trifluoromethane sulphonic acid esters.