64018-24-2Relevant academic research and scientific papers
Light-fluorous TEMPO: reagent, spin trap and stable free radical
Dobbs, Adrian P.,Jones, Peter,Penny, Mark J.,Rigby, Stephen E.
supporting information; experimental part, p. 5271 - 5277 (2009/11/30)
The synthesis of two light-fluorous TEMPO derivatives is reported, along with their fluorous-organic solvent partition coefficients and their ESR spectra. Applications of the fluorous-TEMPO reagents in oxidation reactions and as radical traps are discussed.
Novel light-fluorous TEMPO reagents and their application in oxidation reactions
Dobbs, Adrian P.,Penny, Mark J.,Jones, Peter
scheme or table, p. 6955 - 6958 (2009/04/07)
The synthesis of two light-fluorous TEMPO derivatives is reported, along with their application in oxidation reactions.
Synthesis of 2H,2H-perfluoroalkyl and 2H-perfluoroalkenyl carboxylic acids and amides
Achilefu, Samuel,Mansuy, Laurence,Selve, Claude,Thiebaut, Sylvie
, p. 19 - 26 (2007/10/02)
An efficient and convenient procedure for the synthesis of 2-perfluoroalkyl ethanoic acids by direct oxidation of 2-perfluoroalkyl ethanols with Jones' reagent (CrO3/H2SO4) is described.Treatment of the acids with aqueous sodium hydroxide gave 3-perfluoroalkyl, 3-fluoro-2,3-propenyl carboxylic acids wich may be used for the preparation of the corresponding chlorides and amides. - Keywords: Synthesis; 2-Perfluoroalkyl ethanoic acids; Jones' reagent; NMR spectroscopy; IR spectroscopy
