640273-99-0

Basic information

• Product Name: [Ti6(μ-O)6(O2CPh)6(OCH2C(CH3)3)6]
• CAS NO: 640273-99-0
• Molecular Weight: 1632.82
• Mol File: 640273-99-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ti6(μ-O)6(O2CPh)6(OCH2C(CH3)3)6](CAS DataBase Reference)
• NIST Chemistry Reference: [Ti6(μ-O)6(O2CPh)6(OCH2C(CH3)3)6](640273-99-0)
• EPA Substance Registry System: [Ti6(μ-O)6(O2CPh)6(OCH2C(CH3)3)6](640273-99-0)

Safety Data

• Hazardous Substances Data: 640273-99-0(Hazardous Substances Data)

Upstream product

• 3087-37-4 titanium tetra-n-propoxide 
• 75-84-3 2,2-dimethyl-propanol-1 

Relevant articles and documents

The reaction of iron carboxylates with titanium alkoxides. Isolation and structural characterisation of [Ti6(μ3-O) 6(O2CPh)6(OCH2C(CH3) 3)6]

The reaction of [Fe4(μ3-O)2(O 2CPh)8(py)2] (1) with Ti(OPrn) 4 in toluene yields separate Fe and Ti species each containing both carboxylate and alkoxide groups rather than a bimetallic Fe-Ti complex. The addition of neopentanol to the reaction mixture has enabled [Ti 6(μ3-O)6(O2CPh) 6(OCH2C(CH3)3)6] (3) to be isolated and structurally identified. The compound [Ti6(μ 3-O)4(O2CPh)8(OPrn) 8] (4) has also been characterised and shown not to convert to a {Ti6(μ3-O)6}12+ core compound under the same temperature conditions used in the Fe-Ti reactions.