640279-67-0

Upstream product

• 622-42-4 1-nitro-1-phenylmethane 
• 84312-20-9 (1R,3R,4S)-8-phenylmenthyl glyoxylate 

Downstream Products

• 161759-90-6 (+)-(2S,3R)-methyl 3-(tert-butoxycarbonylamino)-2-hydroxy-3-phenylpropanoate 
• 167275-69-6 methyl (2S)-acetoxy-(3R)-tert-butoxycarbonylamino-3-phenylpropionate 
• 640279-68-1 (2S,3R)-2-Acetoxy-3-tert-butoxycarbonylamino-3-phenyl-propionic acid 
• 685507-98-6 O-[(3R)-tert-butoxycarbonylamino-(2S)-hydroxy-3-phenylpropanoyl]-(1'R,2'S,5'R)-8'-phenylmenthol 
• 685507-99-7 O-[(2S)-acetoxy-(3R)-tert-butoxycarbonylamino-3-phenylpropanoyl]-(1'R,2'S,5'R)-8'-phenylmenthol 

Relevant academic research and scientific papers

Asymmetric Nitroaldol Reaction. Synthesis of Taxotere Side Chain and (-)-Bestatin Using (1R)-8-Phenylmenthyl Glyoxylate

The nitroaldol reaction of (1R)-8-phenylmenthyl glyoxylate (3b) with 1-nitro-1-phenylmethane (4) or with 1-nitro-2-phenylethane (13) led stereoselectively to adducts syn-2b and syn-12b, which were then transformed into the Taxotere side chain and (-)-best

Highly diastereoselective Henry reaction of nitro compounds with chiral derivatives of glyoxylic acid

N-Glyoxyloyl-(2R)-bornane-10,2-sultam and (1R)-8-phenylmenthyl glyoxylate react stereoselectively with simple nitro compounds giving diastereoisomeric nitroalcohols with high asymmetric induction. N-Glyoxyloyl-(2R)-bornane-10,2- sultam 1a is shown to be a