64028-01-9

Basic information

• Product Name: 3,3-dimethyl-2-butanone-2,4,6-triisopropylbenzenesulfonyl-hydrazide
• Synonyms: 3,3-dimethyl-2-butanone-2,4,6-triisopropylbenzenesulfonyl-hydrazide
• CAS NO: 64028-01-9
• Molecular Weight: 380.595
• Mol File: 64028-01-9.mol

Chemical Properties

• CAS DataBase Reference: 3,3-dimethyl-2-butanone-2,4,6-triisopropylbenzenesulfonyl-hydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-dimethyl-2-butanone-2,4,6-triisopropylbenzenesulfonyl-hydrazide(64028-01-9)
• EPA Substance Registry System: 3,3-dimethyl-2-butanone-2,4,6-triisopropylbenzenesulfonyl-hydrazide(64028-01-9)

Safety Data

• Hazardous Substances Data: 64028-01-9(Hazardous Substances Data)

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 39085-59-1 trisylhydrazine 

Downstream Products

• 154595-84-3 1-benzenesulphonyl-2-(1'-hydroxy-2'-t-butylprop-2'-enyl)indole 
• 192513-28-3 1-(1-Benzenesulfonyl-6-methoxy-1H-indol-2-yl)-3,3-dimethyl-2-methylene-butan-1-ol 
• 154595-86-5 1-benzenesulphonyl-2-t-butyl-3-oxo-1,2,3,4-tetrahydrocyclopentindole 
• 154595-85-4 1-benzenesulphonyl-2-(2'-t-butyl-1'-oxoprop-2'-enyl)indole 
• 192513-30-7 4-Benzenesulfonyl-2-tert-butyl-6-methoxy-1,4-dihydro-2H-cyclopenta[b]indol-3-one 
• 192513-33-0 4-Benzenesulfonyl-2-tert-butyl-6-hydroxy-1,4-dihydro-2H-cyclopenta[b]indol-3-one 
• 192513-29-4 1-(1-Benzenesulfonyl-6-methoxy-1H-indol-2-yl)-3,3-dimethyl-2-methylene-butan-1-one 
• 21101-85-9 2,3,3-trimethylbutanenitrile 

Relevant articles and documents

BIOMIMETIC METHYL TRANSFER TO OLEFINS

Conditions have been found under which trisubstituted olefins can be methylated with diaryl methyl sulfonium salts in 2,6-di-t-butylpyridine.The pattern of methylated compounds formed is similar to that of the enzymatic methylation of Δ24 steroids side chains with S-adenosylmethionine as a methyl donor.

Syntheses of 6-substituted truncated Yuehchukene analogues

Facile syntheses of 2-t-butyl-3-(indol-3′-yl)-1,2,3,4-tetrahydrocyclopent[b]indol-6-ol (3), and its 6-methoxy (4) and 6-acetyloxy (5) derivatives are described.

The Conversion of Aldehydes and Ketones via their 2,4,6-Tri-isopropylbenzenesulphonyl Hydrazones into Nitriles containing One Additional Carbon Atom

2,4,6-Tri-isopropylbenzenesulphonyl hydrazones of aliphatic and alicyclic aldehydes and ketones react readily with potassium cyanide in boiling methanol solution to give the corresponding nitriles (containing one more carbon atom than the original aldehyde or ketone) in satisfactory yield. Under the same conditions, benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone gives phenylacetonitrile in very low yield.In some cases, the arenesulphonyl hydrazones may be generated in situ, in methanol solution, from the carbonyl compounds and 2,4,6-tri-isopropylbenzenesulphonohydrazide (11a), thereby constituting a one-pot preparation or the nitriles.