640282-58-2Relevant academic research and scientific papers
Preparation and coordination chemistry of Ph2PNHNHpy
Slawin, Alexandra M.Z.,Wheatley, Joanne,Wheatley, Matthew V.,Woollins, J. Derek
, p. 1397 - 1405 (2008/10/08)
Ph2PNHNHpy (1) can be oxidised to form Ph2P(E)NHNHpy (E = O, S, Se, 2-4) or reacted with appropriate metal complexes such as [PtCl2(cod)], [PtMe2(cod)], [Pd(μCl)(η3-C3H5)]2, [RhCl(cod)]2, [RuCl2(η3:η3-C10 H16)]2, [RuCl2(P-Cy)]2, [IrCp*Cl2]2, and [Cu(MeCN)4][PF6] to give a range of new monodentate complexes. All new compounds have been charactersised by elemental analyses, NMR, IR and mass spec. The X-ray structures of Ph2PNHNHpy, Ph2P(Se)NHNHpy [RuCl2(η3:η3C10 H16)(Ph2PNHNHpy-P)] and [IrCp*Cl2(Ph2PNHNHpy-P)] are reported. Apart from monodentate P coordination all of the structures contain hydrazine based NH hydrogen bonding.
