640283-73-4Relevant academic research and scientific papers
A Combinatorial Synthesis of a Macrosphelide Library Utilizing a Palladium-Catalyzed Carbonylation on a Polymer Support
Takahashi, Takashi,Kusaka, Shin-Ichi,Doi, Takayuki,Sunazuka, Toshiaki,Omura, Satoshi
, p. 5230 - 5234 (2003)
Supported total synthesis: The combinatorial synthesis of a 122-membered macrosphelide library including macrosphelides A, C, E, and F (see picture) has been achieved based on a unique strategy for a three-component coupling utilizing a palladium-catalyzed chemoselective carbonylation and an unprecedented macrolactonization on a polymer support.
Stereoselective synthesis of macrosphelide i
Veena, Bacchu,Sharma, Gangavaram V. M.
, p. 2039 - 2043 (2014/11/08)
An efficient total synthesis of macrosphelide I, has been achieved starting from commercially available chiral materials, ethyl (S)-lactate and methyl (R)-3-hydroxybutyrate. Titanium(IV) promoted the regioselective nucleophilic opening reaction of epoxy a
