640285-92-3

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 179990-59-1 (2S,4R)-4-hydroxy-N-(9'-phenylfluoren-9'-yl)pyrrolidine-2-carboxylic acid methyl ester 

Downstream Products

• 923606-25-1 4-(morpholin-4-yl)-1-phenylsulfonyl-1'-allyl-5'-methyl-2,2'-bipyrrole 
• 923606-23-9 1-[4-(N-benzyl-N-methylamino)-1-(phenylsulfonyl)-1H-pyrrol-2-yl]pentane-1,4-dione 
• 923606-22-8 1-[4-(morpholin-4-yl)-1-(phenylsulfonyl)-1H-pyrrol-2-yl]pentane-1,4-dione 
• 923606-19-3 4-(N-benzyl-N-methylamino)-2-(pent-4-enoyl)-1-(phenylsulfonyl)pyrrole 
• 923606-17-1 4-(morpholin-4-yl)-2-(pent-4-enoyl)-1-(phenylsulfonyl)pyrrole 
• 923606-16-0 4-dimethylamino-2-(pent-4-enoyl)-1-(phenylsulfonyl)pyrrole 
• 923606-08-0 4-(N-benzyl-N-methylamino)-2-(pent-4-enoyl)pyrrole 
• 923606-13-7 4-benzyloxy-2-(pent-4-enoyl)pyrrole 
• 923606-05-7 1-[(2S)-4-oxo-1-(9-phenylfluoren-9-yl)pyrrolidin-2-yl]pent-4-en-1-one 

Relevant academic research and scientific papers

4-Alkoxy- and 4-Amino-2,2′-bipyrrole Synthesis

(Chemical Equation Presented) 4-Alkoxy-2,2′-bipyrroles and the first examples of 4-amino-2,2′-bipyrroles have been synthesized by a diversity-oriented strategy from 4-hydroxyproline. The bipyrrole products offer interesting potential as building blocks fo

One-Pot Synthesis of Homoallylic Ketones from the Addition of Vinyl Grignard Reagent to Carboxylic Esters

(Equation Presented) Fifteen homoallylic ketones have been synthesized in 26-77% yields on treatment of aromatic, aliphatic, and α-amino methyl carboxylates with excess vinylmagnesium bromide and catalytic amounts of a copper salt in THF. α-Amino homoallylic ketones derived from N-protected α-amino esters possessing aliphatic and alcohol side chains were synthesized in ≥98% enantiomeric purity.