64101-09-3Relevant academic research and scientific papers
Synthesis of structure and function diverse α-D-diazoacetates, α-D-diazoacetamides, α-D-diazoketones, and the antibiotic α-D-azaserine
Bew, Sean P.,Ashford, Polly-Anna,Bachera, Dominika U.
, p. 903 - 912 (2013/05/09)
Using 0.1 mol% to 1 mol% potassium carbonate in an acetonitrile-deuterium oxide mixture acts as a 'privileged' reaction system, which at ambient temperature affords, via a one-pot-one-cycle procedure, α-D-diazoacetates, α-D-diazoacetamides, or α-D-diazoke
Anionic Rearrangement in the Gas phase. The Negative Ion Wolff Rearrangement
Lebedev, Albert, T.,Hayes, Roger N.,Bowie, John H.
, p. 1127 - 1129 (2007/10/02)
Product ion studies indicate that the collision-induced loss of N2 from deprotonated aryl diazomethyl ketones yields an ion formed by Wolff rearrangement, e. g.
