64111-00-8Relevant articles and documents
On the mechanism of epoxidation of alkenes with hypochlorite, catalysed by manganese(III) tetraarylporphyrins
Made, A. W. van der,Nolte, R. J. M.,Drenth, W.
, p. 537 - 551 (2007/10/02)
A detailed mechanistic study of the epoxidation of alkenes by the cytochrome-P-450 model sodium hypochlorite/manganese(III) tetraarylporphyrin is presented.From the zero-order rate dependence on alkene concentration and low-temperature-trapping experiment