641144-16-3

Basic information

• Product Name: 10-BROMOANTHRACENE-9-BORONIC ACID
• Synonyms: 10-Bromoanthracene-9-boronic acid;(10-broMoanthracen-9-yl)boronic acid;10-Bromoanthracen-9-boronic acid;9-Bromoanthracen-10-boronic acid;9-Bromoanthracene-10-boronic acid
• CAS NO: 641144-16-3
• Molecular Formula: C₁₄H₁₀BBrO₂
• Molecular Weight: 300.94
• Product Categories: BoronicAcids;Aryl;Boronic Acids;Boronic Acids and Derivatives;blocks
• Mol File: 641144-16-3.mol

Chemical Properties

• Melting Point: 165-169 °C(lit.)
• Boiling Point: 525.3 °C at 760 mmHg
• Flash Point: 271.5 °C
• Appearance: /
• Density: 1.6 g/cm³
• Vapor Pressure: 7.33E-12mmHg at 25°C
• Refractive Index: 1.744
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 8.29±0.30(Predicted)
• CAS DataBase Reference: 10-BROMOANTHRACENE-9-BORONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 10-BROMOANTHRACENE-9-BORONIC ACID(641144-16-3)
• EPA Substance Registry System: 10-BROMOANTHRACENE-9-BORONIC ACID(641144-16-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 641144-16-3(Hazardous Substances Data)

Usage

Uses

Reactant for:Suzuki cross-coupling reactionsPalladium-catalyzed 1,4-addition reactions

InChI:InChI=1/C14H10BBrO2/c16-14-11-7-3-1-5-9(11)13(15(17)18)10-6-2-4-8-12(10)14/h1-8,17-18H

Upstream product

• 121-43-7 Trimethyl borate 
• 523-27-3 9,10-Dibromoanthracene 

Downstream Products

• 1227732-28-6 methyl 2-acetamido-3-(10-bromoanthracen-9-yl)propanoate 
• 121848-75-7 10,10'-dibromo-9,9'-bianthryl 
• 1227732-29-7 methyl 2-acetamido-3-(10-bromoanthracen-9-yl)prop-2-enoate 
• 1567365-76-7 N-octyl-4-(10-bromo-9-anthracenyl)acetanilide 
• 1092390-01-6 9-bromo-10-(4-(naphthalene-1-yl)phenyl)anthracene 

Relevant articles and documents

Supramolecular structures and spontaneous resolution: The case of ortho-substituted phenylboronic acids

The solid state structures of a number of ortho-substituted arylboronic acids, ortho-bromophenyl, ortho-phenylphenyl, pentamethylphenyl, and 10-bromo-9-anthryl, were determined by X-ray diffraction techniques. All boronic acids investigated form dimers in the solid state, but the interconnection of dimers to ribbons differs from that of the parent phenylboronic acid. Pentamethylphenylboronic acid only uses one hydrogen bond but an additional OH-π interaction for connection of dimers, while all others investigated employ two hydrogen bonds for interconnection of dimers to ribbons. 10-Bromo-9-anthrylboronic acid is found to undergo spontaneous resolution of its enantiomers to a racemic conglomerate upon crystallization. The Royal Society of Chemistry.

ASYMMETRIC MONOANTHRACENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE UTILIZING THE SAME

Provided are an asymmetric monoanthracene derivative having a specific structure, a material for an organic EL device comprising the above asymmetric monoanthracene derivative and an organic EL device in which an organic thin film layer comprising a single layer or plural layers including a luminescent layer is interposed between a cathode and an anode, wherein at least one of the above organic thin film layers contains the asymmetric monoanthracene derivative described above in the form of a single component or a mixed component. Provided are an organic electroluminescent (EL) device having a high luminous efficiency and a long life, an asymmetric monoanthracene derivative which materializes the same and a material for an organic EL device.