64128-10-5Relevant academic research and scientific papers
Cobalt-Catalyzed Oxidant-Free Spirocycle Synthesis by Liberation of Hydrogen
Lv, Ningning,Liu, Yue,Xiong, Chunhua,Liu, Zhanxiang,Zhang, Yuhong
, p. 4640 - 4643 (2017)
The first example of oxidant-free cobalt-catalyzed synthesis of five-membered spirocycles is reported from benzimidates and maleimides utilizing nitrobenzene as promoter. In contrast to previously known cobalt-catalyzed oxidative C-H functionalization rea
Rh(III)-Catalyzed [3 + 2] Annulation via C-H Activation: Direct Access to Trifluoromethyl-Substituted Indenamines and Aminoindanes
Chaudhary, Bharatkumar,Auti, Prashant,Shinde, Suchita Dattatray,Yakkala, Prasanna Anjaneyulu,Giri, Deepesh,Sharma, Satyasheel
supporting information, p. 2763 - 2767 (2019/04/30)
The rhodium(III)-catalyzed direct C-H addition and annulation of benzimidates and aldimines with β-(trifluoromethyl)-α,β-unsaturated ketones is described. This protocol provides the facile and efficient formation of various trifluoromethyl-containing inde
Synthesis of Functionalized Indenones via Rh-Catalyzed C-H Activation Cascade Reaction
Lv, Ningning,Chen, Zhengkai,Liu, Yue,Liu, Zhanxiang,Zhang, Yuhong
supporting information, p. 2588 - 2591 (2017/05/24)
An efficient and expeditious protocol for the synthesis of diverse difunctionalized indenones through rhodium-catalyzed C-H activation and multistep cascade reaction of benzimidates and alkenes has been developed. The transformation involves the cleavage and formation of multiple bonds in one pot under mild reaction conditions, and Mn(OAc)2 plays an important role in the reaction.
