64160-40-3Relevant academic research and scientific papers
Kinetics of the Reaction between Ethylperoxy Radicals and Nitric Oxide
Maricq, M. Matti,Szente, Joseph J.
, p. 12374 - 12379 (2007/10/03)
The kinetic of the C2H5O2 + NO -> C2O5O + NO2 reaction is examined by two real-time techniques.NO consumption and NO2 formation are measured using transient diode laser absorption, whereas ethylperoxy loss and ethylnitrite formation are monitored by time-resolved UV spectrometry.Simultaneous fits of the NO and NO2 concentration versus time profiles yield rate constants consistent with the results of the C2H5O2 and C2H5ONO measurements.The combined data yield a rate constant of k5 = (3.1-1.0+1.5)E-12 e (330+/-11)/T cm3 s-1 over the 220-355 K temperature range.The small negative temperature dependence is consistent with the accepted mechanism of the reaction proceeding through a C2H5O2NO adduct.
