64222-37-3Relevant academic research and scientific papers
PYRROLES FROM KETOXIMES AND ACETYLENE. 29. SYNTHESIS OF ALKYLPYRROLES FROM DIALKYLKETOXIMES AND DICHLOROETHANE BY REACTION WITH KOH-DMSO
Trofimov, B. A.,Mikhaleva, A. I.,Vasil'ev, A. N.,Korostova, S. E.,Shevchenko, S. G.
, p. 46 - 49 (2007/10/02)
Treatment of dialkylketoximes with dichloroethane and KOH-DMSO results in the formation of alkylpyrroles in 31-61percent yields.In addition, the corresponding 1-vinylpyrroles are formed simultaneously in yields up to 18percent.The corresponding 1,2-bis(alkylideneiminoxy)ethanes are obtained as side products in the reaction; they result from nucleophilic displacement of chlorine atoms by oximate anions.
