64235-17-2

Basic information

• Product Name: 1,3,7,10-tetramethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane
• CAS NO: 64235-17-2
• Molecular Weight: 231.367
• Mol File: 64235-17-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,7,10-tetramethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,7,10-tetramethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane(64235-17-2)
• EPA Substance Registry System: 1,3,7,10-tetramethyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecane(64235-17-2)

Safety Data

• Hazardous Substances Data: 64235-17-2(Hazardous Substances Data)

Upstream product

• 122-20-3 triisopropanolamine 
• 75-79-6 Methyltrichlorosilane 

Downstream Products

• 122-20-3 triisopropanolamine 
• 2445-53-6 methylsilanetriol 

Relevant articles and documents

A New Method of Synthesis of exo-C-substituted 1-Organylsilatranes. 3-Polyfluoroalkyl- and 4,4-Dimethyl-1-organylsilatranes

Alkyltrichlorosilanes RSiCl3 (R = Me, ClCH2, Et) were brought into reaction with tris(2-hydroxyalkyl)amines (HOCHR1CR2R3)n (HOCH2CH3)3-nN (R1 = H, Me, CF3CH2, C3F7CH2; R2 = H, Me, Et; R3 = H, Me; n = 1-3) to obtain the corresponding exo-C-substituted 1-alkylsilatranes RSi(OCHR1CR2R3)n(OCH 2CH2)3-nN in 50-97% yield. The reaction of 2-hydroxyalkylamines with vinyl or phenyltrichlorosilanes involves cleavage of the Si-C bond, resulting in formation 1-chloro-substituted silatranes in 50-95% yield. According to 1N and 13C NMR data, the presence of two methyl groups in position 4 of the silatrane nucleus does not hinder conformational transformations in the latter.