642462-13-3Relevant articles and documents
Synthesis of aliphatic (E)-α,β-unsaturated amides with high diastereoselectivity from α,β-epoxyamides promoted by SmI 2/HMPA
Concellon, Jose M.,Bardales, Eva
, p. 1523 - 1526 (2007/10/03)
Synthesis of aliphatic (E)-α,β-unsaturated amides 2, in which the C=C bond is di- or trisubstituted, is achieved by using samarium diiodide and HMPA. The starting compounds 1 were easily prepared by the reaction of the corresponding lithium or potassium e