64248-57-3Relevant academic research and scientific papers
Enhancing charge mobilities in selectively fluorinated oligophenyl organic semiconductors: a design approach based on experimental and computational perspectives
Maiti, Buddhadev,Wang, Kunlun,Bhandari, Srijana,Bunge, Scott D.,Twieg, Robert J.,Dunietz, Barry D.
supporting information, p. 3881 - 3888 (2019/04/30)
Fluorination can be used to tune optoelectronic properties at the molecular level. A series of oligophenyls with various difluorinations of the phenyl rings has been synthesized, crystalized, structurally resolved and computationally analyzed for charge m
Fine electronic state tuning of cobaltadithiolene complexes by substituent groups on the benzene ring
Tsukada, Satoru,Kondo, Masataka,Sato, Hironobu,Gunji, Takahiro
, p. 265 - 272 (2016/07/06)
A series of 3,6- and 4,5-dihalogen-substituted 1,2-benzenedithiol (H2bdt) ligands, (3,6-X12-4,5-X22-1,2-H2bdt) (X2 = H, X1 = F (1a), Cl (1b), Br (1c); X1 = H, X2 = Cl (4)), and their cobalt complexes, [Cp?Co(3,6-X12-4,5-X22-1,2-bdt)] (X2 = H, X1 = F (2a), Cl (2b), Br (2c); X1 = H, X2 = Cl (5)), were synthesized by a modified selective thiolation reaction. The 1,2-diphenyl-substituted cobaltadithiolene complex (2d) was also synthesized. The molecular structures of all cobaltadithiolene complexes were determined by single crystal X-ray diffraction analysis. Compounds 2a, 5 and 12 showed unique packing structures with intermolecular interactions that confirmed them as the first examples of half-sandwich-type metalladithiolene complexes with a Cp? ligand. The effects of the benzene substituent type and position on the metalladithiolene ring were investigated using UV-vis spectroscopy measurements and cyclic voltammetry. The results indicate that substitution of halogen atoms at the 3 and 6 position of the benzene ring had a larger effect on the dithiolene ring than substitution at the 4 and 5 positions.
Method for producing tetrakis ( fluoroaryl) borate-magnesium compound
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, (2008/06/13)
Fluoroaryl magnesium halide is reacted with a boron compound so that a molar ratio of the fluoroaryl magnesium halide to the boron compound is not less than 3.0 and not more than 3.7, so as to produce a tetrakis (fluoroaryl) borate·magnesium compound. With this method, there occurs no hydrogen fluoride which corrodes a producing apparatus and requires troublesome waste water treatment.
