64255-47-6Relevant academic research and scientific papers
Up the hill: Selective double-bond isomerization of terminal 1,3-dienes towards Z-1,3-dienes or 2Z,4E-dienes
Puenner, Florian,Schmidt, Anastasia,Hilt, Gerhard
, p. 1270 - 1273 (2012)
Against all odds: Two different cobalt catalyst systems led to the selective isomerization of 1,3-dienes. In the case of the [CoBr 2(py-imine)]-catalyzed reaction, the Z-1,3-diene was formed in a highly selective manner (see scheme). When the catalyst precursor [CoBr 2(dpppMe2)] was applied, a double-bond migration and selective isomerization towards the 2Z,4E-configured 2,4-dienes were observed Copyright
