64269-29-0Relevant academic research and scientific papers
Photochemistry and spectroscopy of "stable organic radicals": Steric and electronic effects in intermolecular photoinduced electron transfer
Canepa,Fox,Whitesell
, p. 3886 - 3892 (2007/10/03)
The intermolecular reactivities of amino-substituted perchlorotriphenylmethyl radicals 1-3 were studied, with particular emphasis on electron transfer (ET) reactions. The natural fluorescence lifetimes and the rates of the electron-transfer quenching were studied with several electron donors and acceptors. Fluorescence quenching studies demonstrate the importance of the redox potentials of the ET pair on the observed steric and electronic properties.
Unique Single-Electron Transfers between Chemically Inert Triphenylmethyl Radicals and Triphenylmethyl Anions
Ballester, Manuel,Pascual, Isabel,Torres, Josep
, p. 3035 - 3044 (2007/10/02)
A number of SET reactions between inert 4-X-tetradecachlorotriphenylmethyl radicals (X-PTM.) and stable tetra-n-butylammonium (Q+) 4-Y-tetradecachlorotriphenylmethides (Q+ Y-PTM:-; X,Y= H, Me, NH2CO, Me2NCO, Ph2
Inert Carbon Free Radicals. 3. Monofunctionalized Radicals from Perchlorotriphenylcarbenium Hexachloroantimonate
Ballester, Manuel,Riera, Juan,Castaner, Juan,Rodriguez, Antonio,Rovira, Concepcion,Veciana, Jaime
, p. 4498 - 4505 (2007/10/02)
Perchlorotriphenylcarbenium hexachloroantimonate (2) is prepared from perchlorotriphenylmethyl radical (PTM; 1) and SbCl5.Salt 2 by hydrolisis or ammonolysis yields perchlorofuchsone (3) or NH-tetradecachlorofuchsonimine (4), respectively, two quinonoid c
