64318-63-4Relevant academic research and scientific papers
HOMOLOGATION OF N-ALKANES USING DIAZOESTERS AND RHODIUM(III)PORPHYRINS. ENHANCED ATTACK ON PRIMARY C-H BONDS.
Callot, H.J.,Metz, F.
, p. 4321 - 4324 (2007/10/02)
Carbethoxycarbene, from ethyl diazoacetate and rhodium(III)porphyrins, inserted into methyl C-H bonds of n-alkenes (C6 to C12) with yields up to 20-25 percent corresponding to a large increase of the primary/secondary selectivity.
