64357-59-1Relevant academic research and scientific papers
Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites
Ramamurthy, V.,Corbin, D. R.,Eaton, D. F.
, p. 5269 - 5278 (2007/10/02)
The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated.Product distributions varied significantly from that observed in benzene.In addition, it differed between various alkali-metal cation-exchanged samples.These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule.Although this study is restricted to ketones, the knowledge gained is expected to be of general value.
MODIFICATION OF PHOTOCHEMICAL REACTIVITY BY ZEOLITES: ROLE OF CATIONS IN CONTROLLING THE BEHAVIOR OF RADICALS GENERATED WITHIN FAUJASITES.
Ramamurthy, V.,Corbin, D. R.,Eaton, D. F.,Turro, N. J.
, p. 5833 - 5836 (2007/10/02)
α-Alkyldibenzylketones included in cation exchanged faujasite type zeolites show photobehavior different from that in isotropic organic solvents.Rearrangement and disproportionation which do not contribute in solution are the major processes within the cavities of faujasites.Cation size plays a major role in controlling the pathway pursued by the primary and the secondary radical pair.
